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At the conclusion of this course, the student should be able to:
1. Identify the various levels of training for dealing with hazardous material incidents and response strategies.
2. Describe transportation methods for hazardous materials; containers, the placarding system, use of the ERG, response information, and isolation guides.
3. Describe the use of hazardous materials in terrorism and the potential targets.
4. Identify the physical & chemical properties of hazardous materials, hazard classes and their exposure hazards.
5. Identify federal and state laws and regulations related to hazardous materials.
6. Describe methods of scene safety, management and the application of the Incident Command System (ICS) at hazardous material incidents.
7. Identify the mandatory notification requirements and the need to communicate with other government agencies.
8. Identify the appropriate levels of PPE their use and limitations in conducting work activities.
9. Identify the appropriate selection and use of countermeasures.
10. Identify the appropriate selection and principles of protective actions.
11. Identify the documentation and disposal requirements associated with a hazardous material incident.
12. Describe and demonstrate the principles of decontamination.
13. Use of the Identification and Hazard Assessment (IDHA) to develop and implement an Incident Action Plan (IAP) for a competent response to a hazardous material incident.
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At the conclusion of this course, the student should be able to safely and competently recognize and respond to a hazardous materials incident by knowing the following:
I. Introduction to Hazmat at the FRO Level
A. Training levels
1. First Responder Awareness (FRA)
2. First Responder Operations (FRO)
3. Hazmat Technician
4. Hazmat Specialist
5. Hazmat Incident Commander (IC)
B. Response Strategies
1. Non-intervention
2. Defensive
3. Offensive
II. Hazmat Transportation, Containers, Placards, Information Sources, and Use of the ERG
A. Transportation of hazmats
1. Trucks
2. Trains
3. Intermodals
4. Shipping
5. Aircraft
B. Containers
1. Non-bulk
2. Bulk
3. Facility containment systems
4. Pipelines
5. Containers at clandestine facilities
C. Placards and information sources
1. Department of Transportation (DOT) United Nations (UN) placards
2. National Fire Protection Administration (NFPA) standard 704 markings
3. Military markings
4. Safety Data Sheets (SDS)
5. Chemical Transportation Emergency Center (CHEMTREC)
6. Poison Control
7. California Environmental Reporting System (CERS)
8. Computer-Aided Management of Emergency Operations (CAMEO)
9. Other computer databases
10. Monitoring equipment
11. Facilities and occupancy type
12. Physical observations
a. Sights
b. Sounds
c. Odors
13. Shipping papers
D. ERG
1. Use
2. Hazard classifications
3. Toxic Inhalation Hazard (TIH)
4. Response information
5. Isolation guides
a. Protective action
b. WMD's
6. Glossary
7. Tables I, II, and III
8. Globally harmonized system (GHS) of classification and their labels
III. Terrorism and Hazmats
A. Motivations
B. Groups and Individuals
C. Terrorism response priorities
D. Types of attacks
1. Chemical
2. Nuclear radiation
3. Biological
4. Explosive
E. Targets
1. Infrastructure
2. Symbolic
3. Civilian
4. Eco-terrorism
5. Agro-terrorism
6. Cyber-terrorism
F. Terrorism case studies
1. Indicators of criminal or terrorist activity
2. Responder safety
a. Toxicity
b. Secondary devices
IV. Hazmat Properties, Hazard Classes, and Exposure Hazards
A. States of matter
B. Physical and chemical changes
1. Physical change
2. Thermal influence
3. Mechanical damage
4. Chemical reaction
5. Boiling liquid expanding vapor explosion (BLEVE)
6. Expansion ratios
C. Hazmat classes
1. Explosives
2. Gases
3. Flammable and combustible liquids
a. Flashpoint
b. Ignition temperature
c. Flammable range
d. Vapor pressure
e. Boiling point
f. Vapor density
g. Specific gravity
h. Solubility
4. Flammable solids
5. Spontaneous combustible
6. Dangerous when wet
7. Oxidizers
8. Organic peroxides
9. Poisons
10. Radiation
11. Corrosives
D. Exposure hazards
1. Exposure versus.contamination
2. Secondary contamination
3. Routes of entry
4. Chronic versus acute exposure
5. Target organs
6. Sensitizers
7. Toxicity
a. Lethal dose 50 (LD50)
b. Lethal concentration 50 (LC50)
8. Use of monitoring equipment
V. State and Federal Hazardous Materials Regulations
A. California Code of Regulations
1. Title 8
2. Title 19
3. Title 22
4. Title 23
5. Title 24
6. Fish and Wildlife Code
B. Federal Laws - Code of Federal Regulations (CFR) 49
C. Enforcement of laws and regulations
VI. Scene Safety, Management, and Initiating Incident Command
A. Arriving safely
1. Upwind, uphill, and upstream
2. Size-up: Chemical ID and hazards
3. FRO PPE limitations
4. Rescue considerations using the ERG
B. Scene management
1. Public isolation distances
a. Small spill or fire
b. Large spill or fire
2. Establishing a perimeter
3. Controlling access points
4. Monitoring weather conditions
5. Identifying storm drains and other conduits
C. Initiating the ICS
1. Command modes
a. Unified command
b. Single command
2. Incident Command (IC) responsibilities
a. Command staff
b. General staff
3. Hazmat group
a. Position functions
b. Training levels
4. Resource typing
a. Type I teams
b. Type II teams
c. Type III teams
5. Outside agency involvement
a. Local
b. State
c. Federal
d. Private
VII. Notification Requirements and Communication with other Government Agencies
A. Notification requirements
1. Dispatch
2. Certified Unified Program Agency (CUPA)
3. State Warning Center
4. National response Center
B. Communicating with governmental agencies
VIII. PPE Levels, Use and Limitations
A. Levels
1. Level A
2. Level B
3. Level C
4. Turnouts
5. Flash protection
B. PPE Use
1. Donning and doffing
2. Work activities
C. Limitations
1. Hazards of PPE
2. Common PPE failures
IX. Countermeasures
A. Absorption
B. Adsorption
C. Blanketing/covering
D. Damming, diking, diverting, and retaining
E. Dilution
F. Dispersion
G. Neutralization
H. Vapor Dispersion
I. Vapor Suppression
X. Protective Action Principles
A. Evacuation
B. Shelter-in-place
C. Rescue operations
XI. Documentation and Disposal Requirements
A. Evidence preservation and sampling
B .Incident Action Plans (IAPs)
C. Rescue and recovery
D. Incident termination
1. Debriefing
2. Critique
3. Written reports
XII. Decontamination (Decon) Methods and Practices
A. Methods
1. Absorption
2. Adsorption
3. Chemical degradation
4. Dilution
5. Disinfection
6. Evaporation
7. Isolation and disposal
8. Neutralization
9. Solidification
10. Sterilization
11. Vacuuming
12. Washing
B. Practices
1. Technical decontamination
2. Emergency decontamination
3. Mass decontamination
4. Secondary decontamination
5. Respiratory decontamination
XIII. Identification Hazard Assessment (IDHA) and Developing an IAP
A. Requirements and functions of the IC
1. Serving as the On-Scene Coordinator
2. Applicable laws and regulations
3. Site safety plans
B. Conducting the IDHA
1. Identifying the substance - Resource materials
a. Written
b. Computer databases
2. Monitoring equipment
3. Assessing the hazard
a. General health and fire hazard
b. Physical and chemical properties
c. Variables and modifying conditions
d. Modeling behavior and outcomes
i. Volume
ii. Concentration
iii. Exposure
iv. Duration
v. Weather
vi. Plume modeling
vii. Populations threatened
viii. Toxicology
ix. Logistical problems
e. Outcome if no actions are taken
C. Developing the IAP
1. Identifying objectives
2. Identifying options
3. Understanding countermeasures
4. PPE
5. Identifying protective actions
6. Pre-incident planning
a. Local response plans
b. Area response plans
7. Agency specific responsibilities
8. Safety briefings
9. Safety practices
a. Buddy system
b. Back-up team
10. Decon options
11. Confined space considerations
a. Atmospheric hazards
i. Oxygen deficient
ii. Oxygen enriched
iii. Explosive atmospheres
iv. Toxic atmospheres
b. Physical hazards
i. Engulfment
ii. Slips and falls
iii. Electrical
iv. Structural
v. Mechanical
D. Implementing the response
1. Command options
a. Single
b. Unified
2. Roles and responsibilities
3. Emergency plan
4. Outside agency support
a. Coast Guard
b. EPA
c. FBI
5. Public Information Officer (PIO)
6. Liaison Officer
7. Joint information center
E. Evaluating progress
F. Terminating the incident
1. Debriefing
2. Conducting a critique
3. Reporting and documenting